
Lithium tartrate (酒石酸锂) is a chemical compound with the formula $mathrm{Li_2C_4H_4O_6}$. It is the lithium salt of tartaric acid, characterized by its white crystalline structure and solubility in water. The compound plays a significant role in industrial and scientific applications due to its unique physicochemical properties.
Chemical Structure
Lithium tartrate consists of two lithium cations ($mathrm{Li^+}$) bonded to a tartrate anion ($mathrm{C_4H_4O_6^{2-}}$), forming a stable ionic lattice. Its synthesis typically involves neutralizing tartaric acid with lithium carbonate or hydroxide.
Industrial Applications
It is widely used as a chiral resolving agent in asymmetric synthesis and pharmaceutical manufacturing. Additionally, lithium tartrate serves as a precursor in lithium-ion battery electrolytes and specialized ceramics.
Laboratory Use
In analytical chemistry, it functions as a buffering agent and chelator in electrochemical studies. Its optical activity also makes it valuable in polarimetry for measuring enantiomeric excess.
Safety and Handling
The compound is classified as an irritant. Proper handling requires protective equipment (gloves, goggles) and adequate ventilation. First-aid measures for exposure include rinsing with water and seeking medical attention.
For authoritative references, consult the Merck Index (化學化工詞典) and IUPAC Compendium of Chemical Terminology.
酒石酸锂是一種含锂的有機酸鹽,以下是其關鍵信息的綜合說明:
化學式:存在兩種形式
無水形式:Li₂C₄H₄O₆(分子量161.95)
一水合物:C₄H₅O₆Li·H₂O(分子量174.04)
CAS號:30903-88-9(一水合物)
外觀:白色結晶固體,易溶于水(0℃時溶解度為42g/100ml)
通過酒石酸(C₄H₆O₆)與碳酸锂(Li₂CO₃)反應,經結晶過程制得。反應式可表示為:
$$
text{C₄H₆O₆} + text{Li₂CO₃} rightarrow text{Li₂C₄H₄O₆} + text{CO₂↑} + text{H₂O}
$$
如需更詳細的生産參數或檢測标準,可參考化源網或搜狗百科等來源。
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