
[物化] 陰極極化
Cathodic polarization behaviors of titanium in seawater were investigated by using potentiodynamic polarization and SEM and XRD.
用電化學動态極化法和SEM、XRD等研究了钛在海水中的陰極極化行為。
The fittest process condition is also made. The electrochemical behavior of the new brighteners is preliminary step stu***d by cathodic polarization and SEM.
通過陰極極化曲線和SEM的測定初步研究了新型氰化鍍銀光亮劑在鍍液中的行為。
It was found apparently from the metal fog that the applied cathodic polarization current can inhibit the electrochemical dissolution of aluminium but is not so effective on the chemical dissolution.
從金屬霧的外觀可以判斷:外加的陰極極化電流能夠抑制金屬的電化學溶解,但是化學溶解作用繼續發生。
The experimental results show that the SCC susceptibility of 7075 aluminum alloy would increase in anodic or cathodic polarization, even under a weak polarization.
試驗結果表明,外加陽極極化和陰極極化都能增加7075鋁合金的應力腐蝕敏感性,即使在弱極化情況下也能顯著增加合金的應力腐蝕敏感性。
The cathodic polarization character of industrial pure titanium in sea water was stu***d by meas of AC impedance technique, galvanostat cathodic charging and dynamic polarization technique.
采用交流阻抗技術結合恒電流陰極充氫和動态陰、陽極極化法,研究了工業純钛在海水中的陰極極化性能。
Results showed that adding of resorcinol in the bath could increase the cathodic polarization obviously and improve the quality of deposit.
結果表明,鍍液中加入添加劑************能顯著增加陰極極化及改善鍍層性能;
The cathodic polarization curves show that the addition of nanoparticulates has changed the electrodeposition process of host metal.
陰極極化曲線表明納米微粒的加入改變了基質金屬電沉積的過程。
Both anodic and cathodic polarization curves have been plotted and the mechanism of electrode reactions is also discussed.
根據測定的極化曲線,對陰、陽極過程的反應機理進行了初步探讨。
Cathodic polarization curve and cyclic voltammetric curve of sulfate copper plating solution are determined with 1286 electrochemical interface and rotating disc electrode.
采用1286電化學接口及旋轉圓盤電極測定了硫酸銅鍍液陰極極化曲線和循環伏安曲線。
Experiments show that the corrosion of steels under disbonded holiday on free corrosion potential is heavier than that on cathodic polarization potential on shorter immersing time.
試驗結果表明,在較短的浸泡時間裡,在陰極極化電位下塗層缺陷下方金屬基體的腐蝕程度低于在自然腐蝕電位下的腐蝕程度;
The result showed that cathodic polarization increases with the addition of complexant trisodium citrate and that formation of the alloy deposit is facilitated by addition of sodium hypophosphite.
認為在鎮液中加入配體檸檬酸鈉可以提高陰極極化,加入*********鈉有利于合金鍍層的形成。
Through adding assistant complexing agent and controlling initial current density, cathodic polarization was intensified in cyanide-free electrolyte.
通過添加輔助絡合劑和控制起始電流密度的方法,可以增強無氰電鍍時陰極的極化。
Cathodic polarization was also stu***d.
本實驗還研究了陰極極化法。
Its property of electrochemical catalyzed hydrogen evolution has been stu***d by means of cathodic polarization curves, A. C. impedance technique, and its surface morphology was observed with SEM.
通過陰極極化曲線、交流阻抗等電化學技術研究其析氫催化性能,并用掃描電鏡觀察電極的表面形貌。
Voltammetric determination of nickel disk cathodic polarization curve in chromating bath is presented.
采用伏安法測量鎳盤電極在鉻酸鈍化液中的陰極極化曲線。
Cathodic polarization and current time curves were measured, and deposition potential was selected.
測量了電沉積過程中的陰極極化曲線及電流 -時間曲線 ,确定了沉積電位 ;
Secondly, the cathodic polarization curve and electrochemical impedance spectra of co-deposition of CeO2 nanoparticles and metal nickel were stu***d.
第二,研究了CeO2納米顆粒與電解液中金屬離子共沉積的陰極極化曲線和電化學阻抗譜。
Cathodic protection; Electrochemical impedance spectroscopy; Polarization curve; Protection potential; Embedded systems;
陰極保護;電化學阻抗譜;極化曲線;保護電位;嵌入式系統;
The effect of the TPB zone on the cathodic process of metals was stu***d by steady-state polarization test.
采用穩态極化技術研究了三相線長度、寬度及溶液濃度在金屬腐蝕陰極過程中的作用。
Using polarization curve testing, EGP and DTGP could resist cathodic and anodic, which are cathodic and anodic corrosion inhibitors.
極化曲線法證明該緩蝕劑主要是通過抑制金屬的陰極和陽極反應而起到緩蝕作用。
Potentiodynamic polarization results suggest that the agents have inhibition effect both on anodic reaction and cathodic reaction.
動電位極化曲線測試的結果說明該鎢系水處理劑對陽極、陰極均有抑制作用。
Introduced the KR2 polarization probe's structure, the principle and application in the pipeline cathodic protection survey. Pointed out that polarize probe will substitute for reference electrode.
型極化探頭的結構、原理和在管道陰極保護測量上的應用。指出極化探頭将取代傳統的參比電極。
The effects of soil resistivity, polarization characteristic of tank bottom, depth of anode, distance between anode and tank on cathodic protection potential distribution of tank bottom are stu***d.
研究了土壤電阻率、罐底的極化特性、陽極的埋深、與罐距離及數量等因素對罐底外側陰極保護電位分布的影響,并将模拟結果與實測數據進行了對比。
By polarization curves measurements, it was clear that the inhibitor PC-602 inhibited both the cathodic and anodic processes of the corrosion reactions.
電化學方法測試結果證明,“PC-602”是對電極的陰極和陽極電化學過程都有抑制作用的混合型緩蝕劑。
The reason why water glass can enhance the cathodic polarization is due to the formation of mixed ligand complexes.
水玻璃增大鍍液的陰極極化作用是由于鋅能與矽結合成混合配體絡合物的緣故。
Both the cathodic polarization curves and the scanning electro-micrographs of the zinc deposits show that these compounds are beneficial effect in achieving a bright, uniform zinc plate.
鍍液的陰極極化曲線與鋅鍍層的掃描電子顯微圖均表明:這些化合物對獲得光亮均勻鋅鍍層起很好的作用。
陰極極化(Cathodic Polarization)是電化學中的一個重要概念,指在外加電流作用下,陰極的電極電位偏離其自然平衡電位向更負方向移動的現象。這種現象通常發生在金屬腐蝕或電化學沉積過程中,通過抑制陰極還原反應(如氧還原或氫離子還原)來減緩金屬溶解速率,從而實現腐蝕防護。
其核心機制涉及以下兩點:
在工程實踐中,陰極極化被廣泛應用于海洋設施(如船舶、石油平台)的防腐保護,以及锂電池、燃料電池等新能源器件的性能優化。美國腐蝕工程師協會(NACE)标準指出,将鋼結構極化至-0.85 V(相對于銅/硫酸銅電極)可有效抑制鐵基材料的腐蝕反應。
該理論的基礎可追溯至1930年代Wagner和Traud提出的混合電位理論,相關數學模型可表示為: $$ E = E_{eq} - eta_c eta_c = frac{RT}{alpha nF} lnleft(frac{i}{i_0}right) $$ 其中$eta_c$為陰極過電位,$i$為電流密度,$i_0$為交換電流密度。
陰極極化(cathodic polarization)是電化學中的一個重要概念,指在外加電流作用下,陰極的電極電位偏離其自然平衡狀态的現象。這種現象通常表現為陰極電位向更負的方向移動,導緻電流密度降低,從而減緩金屬的腐蝕速率。
基本定義
陰極極化是電極極化的一種類型,特指陰極(還原反應發生的電極)在通電後電位的變化。當外部電流通過陰極時,電極表面電荷分布改變,導緻其實際電位偏離平衡電位(即極化)。
相關參數與特性
應用領域
陰極極化的程度受多種因素影響,包括電解質成分、溫度、電流密度等。例如,在含有緩蝕劑的溶液中,陰極極化可能增強,從而更有效地抑制金屬腐蝕。此外,極化現象的研究也為理解電極反應動力學提供了理論依據。
如需進一步了解實驗方法或具體應用案例,可參考(動電位掃描法)及(極化曲線分析)。
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