
原子吸收光譜測定法
The calcium content and different components of calcium in the soil and in Chinese olive organs were analyzed by atomic absorption spectrometry.
本研究用原子吸收光譜法分析了果園土壤及橄榄樹體各器官中鈣量和不同組分鈣的含量。
The amounts of cadmium and lead in the samples were determined by atomic absorption spectrometry with the deuterium lamp for the deduction of background absorption.
取適量的乳濁液制成試液,注入石墨爐中,以氘燈扣除背景吸收,石墨爐原子吸收光譜法的快速測定鉛和镉。
In order to enlarge the range of analyzing elements in flame atomic absorption spectrometry, using this kind of high temperature flame to carry out the atomic absorption analysis is suggested.
并對原子化系統和安全提出要求,建議開展這種高溫火焰的原子吸收分析工作,以擴大火焰原子吸收分析元素的範圍。
The flow injection separation and preconcentration techniques combined with atomic absorption spectrometry (AAS) as well as their applications are reviewed with 86 references.
對流動注射線上分離濃集與原子吸收光譜連用技術及其應用作了綜述。 引用文獻86篇。
The contents of trace elements in toenail have been determined by flame atomic absorption spectrometry.
應用火焰原子吸收光譜法測定了人趾甲樣品的微量元素含量;
Foodstuffs - Determination of trace elements - Determination of lead, cadmium, chromium and molybdenum by graphite furnace atomic absorption spectrometry (GFAAS) after pressure digestion.
食品。痕量元素的測定。食品經壓煮後用石墨爐原子吸收光譜法測定鉛、镉、鉻和钼。
The content of microelements such as calcium, magnesium iron, manganese, zinc, copper, cobalt, potassium in the seeds of lotus were determined using flame atomic absorption spectrometry.
蓮子經過硝酸、*********處理後,用火焰原子吸收光譜法測定了蓮子中的鎂、鐵、錳、鋅、銅、钴、鉀、鈣等金屬元素含量。
The conditions and interference restraint for determining trace arsenic in alloy steel by graphite furnace atomic absorption spectrometry were researched.
研究了石墨爐原子吸收法測定合金鋼中痕量砷的實驗條件和幹擾抑制方法。
A method for the determination of trace thallium in soil samples by graphite furnace atomic absorption spectrometry after preconcentration with polyurethane foam has been developed.
本文論述了一種聚氨酯泡塑預富集—石墨爐原子吸收分光光度法測定土壤樣品中痕量铊的方法。
This paper reported a method for the direct determination of aluminum in soil samples by air acetylene flame atomic absorption spectrometry.
本文建立了一種用空氣-乙炔火焰原子吸收法直接測定土壤中鋁的分析方法。
Trace cadmium in the calcium salt reagents was determined by flame atomic absorption spectrometry after separation and enrichment with sulfhydryl cotton.
采用巯基棉分離富集鈣鹽試劑中的痕量镉,用火焰原子吸收光譜法進行測定。
Hair zinc value of 1008 preschool children from Shijiazhuang city of Hebei province were estimated by atomic absorption spectrometry.
本文采用原子吸收光譜法測定了河北省石家莊市1008例學齡前兒童的發鋅值。
Chromium in serum and urine of healthy normal people and diabetic patients was determined by graphite atomic absorption spectrometry.
研究了石墨爐原子吸收光譜法測定糖尿病人和健康人血清及尿中微量的鉻。
Objective To establish a method for determination of aluminum in diluted milk samples by graphite furnace atomic absorption spectrometry with furnace interior direct digestion.
目的建立一種無需事先消化測定牛奶稀釋樣中的鋁的爐内直接消化石墨爐原子吸收法。
Cr and Be in mushroom and Tea were determined by transverse heated graphite furnace atomic absorption spectrometry.
采用橫向加熱石墨爐原子吸收法測定蘑菇、茶葉中的鉻和铍。
A method for the determination of arsenic in ilmenite by graphite furnace atomic absorption spectrometry (GFAAS) with microwave digestion and ion exchange resin separation was established.
建立了微波消解處理樣品、離子交換樹脂分離富集,石墨爐原子吸收光譜法測定钛鐵礦中砷的方法。
Ginseng samples were digested by microwave digestion, copper and iron were determined by atomic absorption spectrometry.
采用微波消解樣品和火焰原子吸收光度法,測定了人參中的銅、鐵含量。
Methods The visions of 168 middle school students were tested with logarithmic visual chart. The serum levels of zinc, copper and selenium were determined by atomic absorption spectrometry.
方法采用對數視力表,對168名中學生進行視力檢測,并根據性别、視力分組,采用原子吸收法對被試者血清鋅、銅、硒含量進行測定。
Flow injection serial dilution techniques was combined with atomic absorption spectrometry (AAS) techniques to determine Ca in acid rain without samples' dilution. This method was fast and ******.
提出了應用流動注射梯度稀釋法與原子吸收光度法相結合,樣品不經稀釋便可同時測定酸雨中不同濃度的鈣。方法快速簡便。
In this article, the recent advances of the application of tungsten coils in electrothermal atomic absorption spectrometry are reviewed with 49 references.
本文主要評述了近年來鎢絲在電熱原子吸收光譜分析中的應用,引用文獻49篇。
Methods: Mice were exposed to acetate lead. The lead contents of blood and epididymis were determined by atomic absorption spectrometry.
方法:小鼠以*********染毒,采用原子吸收分光光度法測定其血鉛及附睾組織鉛含量;
Coating antimony content is measured by atomic absorption spectrometry, which is accurate and easy to operate.
鍍層中銻含量采用原子吸收光譜法測定,具有準确和方便的優點。
A method for the determination of Pd and Pt in catalyst by graphite furnace atomic absorption spectrometry is introduced, sulfhydryl cotton column is used to separate interferential elements.
介紹應用石墨爐原子吸收法測定催化劑中钯和鉑的分析方法,及可将幹擾元素去除的巯基棉柱分離法。
Determination of the chemical nature of the macrophage inclusions by nuclear microprobe, X-ray microanalysis and atomic absorption spectrometry showed that they were composed of aluminium salts.
用核微拭子、X線微量分析和原子吸收光譜法對巨噬細胞包涵體的化學性質進行分析,發現其含有鋁鹽。
原子吸收光譜法(Atomic Absorption Spectrometry, AAS)是一種用于測定樣品中特定金屬元素含量的高靈敏度分析技術。其核心原理基于基态原子蒸氣對特定波長光輻射的選擇性吸收。以下是詳細解釋:
基本原理
當處于基态的原子受到特定波長的光輻射時,會吸收能量躍遷至激發态。每種元素都有其獨特的吸收波長(共振線)。通過測量特定波長光被樣品原子蒸氣吸收的程度(吸光度),并與已知濃度的标準溶液進行比較,即可定量測定樣品中該元素的含量。其定量基礎遵循朗伯-比爾定律(Lambert-Beer's Law):
$$
A = log(frac{I_0}{I}) = varepsilon b c
$$
其中,$A$ 為吸光度,$I_0$ 和 $I$ 分别為入射光和透射光強度,$varepsilon$ 為摩爾吸光系數,$b$ 為吸收光程長度,$c$ 為待測元素濃度。
儀器組成
主要部件包括:
主要應用領域
AAS 因其高靈敏度和選擇性,廣泛應用于:
優勢與局限
權威參考資料:
原子吸收光譜法(Atomic Absorption Spectrometry,AAS)是一種用于元素定量分析的儀器分析方法,其核心原理是通過測量氣态基态原子對特定波長光的吸收程度來确定樣品中元素的含量。以下是詳細解釋:
原子吸收光譜法基于原子中電子能級躍遷的特性。當光源發出的特征輻射通過原子化後的樣品蒸氣時,基态原子會選擇性吸收與其能級差匹配的特定波長光,導緻光強度減弱。通過測量吸光度變化,可推算元素濃度。
根據朗伯-比爾定律,吸光度(A)與元素濃度(C)成正比: $$ A = KC $$ 其中,K為與實驗條件相關的常數。通過标準曲線法可定量未知樣品濃度。
例如,在環境監測中,流動注射氫化物原子吸收法可檢測河流沉積物的砷和汞,檢出限低至2ng/L,精密度和準确度均表現優異。
原子吸收光譜法通過基态原子的選擇性吸光實現元素定量,兼具高靈敏度與準确性,是痕量分析的重要工具。其技術分支(如氫化物法、石墨爐法)進一步擴展了應用範圍。
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