
原子吸收光谱测定法
The calcium content and different components of calcium in the soil and in Chinese olive organs were analyzed by atomic absorption spectrometry.
本研究用原子吸收光谱法分析了果园土壤及橄榄树体各器官中钙量和不同组分钙的含量。
The amounts of cadmium and lead in the samples were determined by atomic absorption spectrometry with the deuterium lamp for the deduction of background absorption.
取适量的乳浊液制成试液,注入石墨炉中,以氘灯扣除背景吸收,石墨炉原子吸收光谱法的快速测定铅和镉。
In order to enlarge the range of analyzing elements in flame atomic absorption spectrometry, using this kind of high temperature flame to carry out the atomic absorption analysis is suggested.
并对原子化系统和安全提出要求,建议开展这种高温火焰的原子吸收分析工作,以扩大火焰原子吸收分析元素的范围。
The flow injection separation and preconcentration techniques combined with atomic absorption spectrometry (AAS) as well as their applications are reviewed with 86 references.
对流动注射在线分离浓集与原子吸收光谱连用技术及其应用作了综述。 引用文献86篇。
The contents of trace elements in toenail have been determined by flame atomic absorption spectrometry.
应用火焰原子吸收光谱法测定了人趾甲样品的微量元素含量;
Foodstuffs - Determination of trace elements - Determination of lead, cadmium, chromium and molybdenum by graphite furnace atomic absorption spectrometry (GFAAS) after pressure digestion.
食品。痕量元素的测定。食品经压煮后用石墨炉原子吸收光谱法测定铅、镉、铬和钼。
The content of microelements such as calcium, magnesium iron, manganese, zinc, copper, cobalt, potassium in the seeds of lotus were determined using flame atomic absorption spectrometry.
莲子经过硝酸、*********处理后,用火焰原子吸收光谱法测定了莲子中的镁、铁、锰、锌、铜、钴、钾、钙等金属元素含量。
The conditions and interference restraint for determining trace arsenic in alloy steel by graphite furnace atomic absorption spectrometry were researched.
研究了石墨炉原子吸收法测定合金钢中痕量砷的实验条件和干扰抑制方法。
A method for the determination of trace thallium in soil samples by graphite furnace atomic absorption spectrometry after preconcentration with polyurethane foam has been developed.
本文论述了一种聚氨酯泡塑预富集—石墨炉原子吸收分光光度法测定土壤样品中痕量铊的方法。
This paper reported a method for the direct determination of aluminum in soil samples by air acetylene flame atomic absorption spectrometry.
本文建立了一种用空气-乙炔火焰原子吸收法直接测定土壤中铝的分析方法。
Trace cadmium in the calcium salt reagents was determined by flame atomic absorption spectrometry after separation and enrichment with sulfhydryl cotton.
采用巯基棉分离富集钙盐试剂中的痕量镉,用火焰原子吸收光谱法进行测定。
Hair zinc value of 1008 preschool children from Shijiazhuang city of Hebei province were estimated by atomic absorption spectrometry.
本文采用原子吸收光谱法测定了河北省石家庄市1008例学龄前儿童的发锌值。
Chromium in serum and urine of healthy normal people and diabetic patients was determined by graphite atomic absorption spectrometry.
研究了石墨炉原子吸收光谱法测定糖尿病人和健康人血清及尿中微量的铬。
Objective To establish a method for determination of aluminum in diluted milk samples by graphite furnace atomic absorption spectrometry with furnace interior direct digestion.
目的建立一种无需事先消化测定牛奶稀释样中的铝的炉内直接消化石墨炉原子吸收法。
Cr and Be in mushroom and Tea were determined by transverse heated graphite furnace atomic absorption spectrometry.
采用横向加热石墨炉原子吸收法测定蘑菇、茶叶中的铬和铍。
A method for the determination of arsenic in ilmenite by graphite furnace atomic absorption spectrometry (GFAAS) with microwave digestion and ion exchange resin separation was established.
建立了微波消解处理样品、离子交换树脂分离富集,石墨炉原子吸收光谱法测定钛铁矿中砷的方法。
Ginseng samples were digested by microwave digestion, copper and iron were determined by atomic absorption spectrometry.
采用微波消解样品和火焰原子吸收光度法,测定了人参中的铜、铁含量。
Methods The visions of 168 middle school students were tested with logarithmic visual chart. The serum levels of zinc, copper and selenium were determined by atomic absorption spectrometry.
方法采用对数视力表,对168名中学生进行视力检测,并根据性别、视力分组,采用原子吸收法对被试者血清锌、铜、硒含量进行测定。
Flow injection serial dilution techniques was combined with atomic absorption spectrometry (AAS) techniques to determine Ca in acid rain without samples' dilution. This method was fast and ******.
提出了应用流动注射梯度稀释法与原子吸收光度法相结合,样品不经稀释便可同时测定酸雨中不同浓度的钙。方法快速简便。
In this article, the recent advances of the application of tungsten coils in electrothermal atomic absorption spectrometry are reviewed with 49 references.
本文主要评述了近年来钨丝在电热原子吸收光谱分析中的应用,引用文献49篇。
Methods: Mice were exposed to acetate lead. The lead contents of blood and epididymis were determined by atomic absorption spectrometry.
方法:小鼠以*********染毒,采用原子吸收分光光度法测定其血铅及附睾组织铅含量;
Coating antimony content is measured by atomic absorption spectrometry, which is accurate and easy to operate.
镀层中锑含量采用原子吸收光谱法测定,具有准确和方便的优点。
A method for the determination of Pd and Pt in catalyst by graphite furnace atomic absorption spectrometry is introduced, sulfhydryl cotton column is used to separate interferential elements.
介绍应用石墨炉原子吸收法测定催化剂中钯和铂的分析方法,及可将干扰元素去除的巯基棉柱分离法。
Determination of the chemical nature of the macrophage inclusions by nuclear microprobe, X-ray microanalysis and atomic absorption spectrometry showed that they were composed of aluminium salts.
用核微拭子、X线微量分析和原子吸收光谱法对巨噬细胞包涵体的化学性质进行分析,发现其含有铝盐。
原子吸收光谱法(Atomic Absorption Spectrometry, AAS)是一种用于测定样品中特定金属元素含量的高灵敏度分析技术。其核心原理基于基态原子蒸气对特定波长光辐射的选择性吸收。以下是详细解释:
基本原理
当处于基态的原子受到特定波长的光辐射时,会吸收能量跃迁至激发态。每种元素都有其独特的吸收波长(共振线)。通过测量特定波长光被样品原子蒸气吸收的程度(吸光度),并与已知浓度的标准溶液进行比较,即可定量测定样品中该元素的含量。其定量基础遵循朗伯-比尔定律(Lambert-Beer's Law):
$$
A = log(frac{I_0}{I}) = varepsilon b c
$$
其中,$A$ 为吸光度,$I_0$ 和 $I$ 分别为入射光和透射光强度,$varepsilon$ 为摩尔吸光系数,$b$ 为吸收光程长度,$c$ 为待测元素浓度。
仪器组成
主要部件包括:
主要应用领域
AAS 因其高灵敏度和选择性,广泛应用于:
优势与局限
权威参考资料:
原子吸收光谱法(Atomic Absorption Spectrometry,AAS)是一种用于元素定量分析的仪器分析方法,其核心原理是通过测量气态基态原子对特定波长光的吸收程度来确定样品中元素的含量。以下是详细解释:
原子吸收光谱法基于原子中电子能级跃迁的特性。当光源发出的特征辐射通过原子化后的样品蒸气时,基态原子会选择性吸收与其能级差匹配的特定波长光,导致光强度减弱。通过测量吸光度变化,可推算元素浓度。
根据朗伯-比尔定律,吸光度(A)与元素浓度(C)成正比: $$ A = KC $$ 其中,K为与实验条件相关的常数。通过标准曲线法可定量未知样品浓度。
例如,在环境监测中,流动注射氢化物原子吸收法可检测河流沉积物的砷和汞,检出限低至2ng/L,精密度和准确度均表现优异。
原子吸收光谱法通过基态原子的选择性吸光实现元素定量,兼具高灵敏度与准确性,是痕量分析的重要工具。其技术分支(如氢化物法、石墨炉法)进一步扩展了应用范围。
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