
[高分子] 縮聚反應;縮聚合
Cardanol -aldehyde ferric polymers were prepared by condensation polymerization with formaldehyde, n-butyl aldehyde, furfural and iron trichloride.
以溶液縮聚法,由腰果酚分别與甲醛、*********、糠醛和************制備了腰果酚醛鐵聚合物。
Microcapsules of Phthalocyanine Green G with urea-formaldehyde resin wall were prepared by in-situ condensation polymerization reaction with acid catalyzer.
用原位聚合法制備以脲醛樹脂為壁材的酞菁綠G顔料微膠囊,采用了酸催化下的縮聚反應工藝。
Microcapsules of pendimethalin with a urea-formaldehyde resin wall were prepared by an in-situ condensation polymerization reaction in aqueous medium.
研究了分散、乳化條件及成囊工藝對以脲醛樹脂為壁材制備二甲戊樂靈微膠囊狀态的影響。
Influence of the reaction conditions on the condensation polymerization at the presence of DBTL was discussed.
讨論了二月桂酸*********錫催化劑存在下反應條件對縮聚反應的影響。
In condensation polymerization, the monomer need have only one functional group -the presence of two or more functional groups usually leads to the production of cross-linked addition polymers.
在縮聚合作用中,單體僅需有一個功能團,兩個或兩個以上功能團的出現經常會導緻交聯附加聚合物的生成物。
A new type of phenolic resin adhesive for casting was prepared by condensation polymerization of furfuryl alcohol and the reaction product between phenol, phenylphenol, urea and formaldehyde.
苯酚、************、尿素與甲醛的反應産物進一步與糖醇縮聚生成新型鑄造用改性酚醛樹脂粘結劑。
A bakelite resin adhesive was synthesized with raw materials of phenol, resorcinol, formaldehyde by the method of one stage process condensation polymerization.
研究了以************、苯酚、甲醛為原料,改用一步共縮聚的方法合成************酚醛樹脂膠粘劑;
There are two main methods to synthesis PLA, ring- opening polymerization of lactide and condensation polymerization of lactic acid.
聚乳酸的合成主要有兩種方法:丙交酯的開環聚合和乳酸直接縮聚。
There are two main methods to synthesis PLA, condensation polymerization of lactic acid and ring-opening polymerization of lactide.
聚乳酸的合成主要有兩種方法:乳酸直接縮聚和丙交酯的開環聚合。
It also shows that methylamide can restrain the hydrolysis of alcohol salt, increase the rate of condensation polymerization and keep the film from dry crack.
甲酰胺可以抑制醇鹽水解,提高縮聚速率并避免薄膜幹燥開裂。
The double- melt behavior, thermal stability of soild state condensation polymerization of PET and the crystallization, expansibility of PET bottle have been stu***d by DSC, TGA and TMA.
應用DSC、TGA和TMA研究了固相聚合PET 樹脂的雙重熔融行為、熱穩定性及瓶坯、包裝瓶的結晶性能和膨脹性。
Water-soluble chitosan was prepared by modification of chitosan with maleic anhydride, and then nylon 64 was grafted onto it by condensation polymerization.
通過************酰化改性制取水溶性殼聚糖,利用沉澱縮聚方法将尼龍接枝于該水溶性殼聚糖上。
More recently, its applications have been expanded to supervise chemical reactions, especially the addition polymerization, condensation polymerization, cross-linking, decomposition course and etc.
近來,介電譜技術又被用于監測化學反應,特别是加聚、縮聚、交聯以及降解過程等等。
Two types of polymerization are recognized: (1)condensation polymerization and (2) addition polymerization.
人們已知有兩種聚合方式:(1)縮聚,(2)加聚。
In condensation polymerization, the monomer will affect the purity of the molar ratio of functional groups, so that the molecular weight deviates from the set value.
在縮合聚合中,單體的純度會影響到官能團的摩爾比,從而使聚合物的分子量偏離設定值。
The results show that high-molecular weight PLA can be prepared by the direct melt condensation polymerization at suitable technological condition and the product has good biodegradability.
結果表明:采用適當的工藝能通過熔融縮聚法制備出高分子質量的聚乳酸,且具有良好的生物降解性能。
They are usually prepared from equivalent amounts of glycols and dibasic carboxylic acids, which undergo condensation polymerization to produce the polyester and water.
通常由等當量的甘醇和二元羧酸制備,它們經過聚合作用而生成聚酯和水。
Hybrid UV curing system includes free radical cationic hybrid UV curing system, Free radical condensation polymerization system and free radical free radical system.
混雜光固化體系包括自由基陽離子混雜光固化體系、自由基縮聚混雜體系和自由基自由基混雜體系等。
DCPD type unsaturated polyester resin prepared by using semi condensation polymerization method is proposed.
本文用半縮聚法合成***************型不飽和聚酯樹脂。
In condensation polymerization, each monomer unit must have at least two functional groups.
即,單體是一個單體單元,而二聚體是兩個單體單元。
The formulation. process flow and conditions in the production of nylon 66 with continuous condensation polymerization are introduced.
介紹用連續縮聚法生産尼龍66的配方,工藝流程及條件。
It was thought that the reaction was a positive ion-typed condensation polymerization catalyzed by acid.
該反應為酸催化下的陽離子型縮聚反應。
縮聚反應(condensation polymerization)是一種通過單體分子間官能團縮合生成高分子聚合物的化學過程。該反應過程中,單體之間通過脫去小分子副産物(如水、醇或氯化氫等)形成共價鍵,逐步增長為長鍊聚合物。例如,聚酯和尼龍的合成均屬于典型的縮聚反應(來源:美國化學會ACS)。
縮聚反應的核心機制涉及兩個或更多官能團的相互作用。例如,羧酸與醇反應生成酯鍵時,會脫去一分子水。這種逐步聚合的特點使得分子量隨時間緩慢增加,最終産物的分子量分布較寬(來源:英國皇家化學會RSC)。常見的縮聚反應類型包括聚酯化反應(如PET塑料)和聚酰胺反應(如尼龍-6,6)。
該反應在工業中應用廣泛:
縮聚反應與加聚反應的關鍵區别在于副産物的生成,這一特性使其在可控合成功能高分子材料領域具有獨特優勢(來源:MIT開放式課程-高分子化學章節)。
Condensation polymerization(縮聚反應) 是一種通過單體分子間反複縮合生成高分子聚合物并伴隨小分子副産物(如水、醇等)的化學反應。以下是其核心要點:
定義與機理
縮聚反應中,單體通常含有兩個或以上可反應的官能團(如羧酸與醇、胺與羧酸等),通過脫去小分子(如H₂O、HCl)逐步連接成長鍊聚合物。例如,聚酯(如PET)的合成就是典型的縮聚反應。
特點
分類與實例
與加聚反應的區别
縮聚反應伴隨小分子釋放,而加聚反應(如聚乙烯的合成)無副産物,僅通過不飽和鍵打開連接。
如需進一步了解具體反應條件或工業應用,可參考高分子化學教材或專業文獻。
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